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INDIAN INSTITUTE OF TECHNOLOGY GUWAHATI

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Binary Vapour Liquid Equiibrum

  • Theory
  • Procedure
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PROCEDURE :

  1. Cleaning the Setup : The setup is cleaned to start a new Experiment.

  2. Mixing in given ratios : A mixture of benzene and toluene is prepared and put into the flask.

  3. Power is Supplied : Then the power is supplied and the mixture begins to boil.

  4. Equilibrium is Reached: After some time equilibrium is reached, this is marked by steady temperature in both the phases.

  5. Measuring RI : Samples of condensed vapor and liquid are taken. To calculate the composition we need to measure the refractive index of the sample and look into the chart.

 

Fig : 1.3 Mole fraction Vs Temperature plot

 

NOMENCLATURE :

   x*    equilibrium composition of benzene in liquid phase
   y*
   equilibrium composition of benzene in vapor phase
   Teq
   equilibrium temperature
   Tt, boil
   Boiling temperature of pure Toluene
   Tb, boil
   Boiling temperature of pure Benzene
   a
   Relative Volatility

 

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